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Synthesis, Characterization, and Self-Assembling Properties of New Amphiphilic Dendrons Bearing Branched TRIS-Derived Oligomers as Polar Head Groups 

Desgranges, S.; Lacanau, V.; Bonneté, F.; Soulié, M.; Bihel, F.; Bourgeois, D.; Contino-Pépin, C. Synthesis, Characterization, and Self-Assembling Properties of New Amphiphilic Dendrons Bearing Branched TRIS-Derived Oligomers as Polar Head Groups. Macromolecules 2024 https://doi.org/10.1021/acs.macromol.3c02388.
 

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Synthesis and characterization of a new family of dendritic surfactants called DendriTAC (single- or double-tailed surfactants containing hydrophobic hydrocarbon or fluorocarbon chains grafted onto TRIS-derived oligomeric polar heads).

Structural parameters of the surfactant assemblies in solution assessed by SAXS and DLS => self-assembling properties of H/F-DendriTACs are in agreement with usual trends of surfactant assemblies.
Great structural versatility => can provide highly tunable self-assembly morphologies that can be adapted to specific applications.